2021-2024
26.
Iridium-Catalyzed Asymmetric Allylation of Indoles via Kinetic Resolution of 1-Alken-4-yn-3-ols
Takahiro Sawano,Yuki Yasumura, Kyohei Kuwabara, Hikaru Sugiura, Kana Takahashi, Eri Ishikawa, Ryo Takeuchi, Synlet., 2023, 34, 2491-2495. [LINK]
25.
Iridium-Catalyzed Branch-Selective Hydroalkylation of Simple Alkenes with Malonic Amides and Malonic Esters
Takahiro Sawano, Masaki Ono, Ami Iwasa, Masaya Hayase, Juri Funatsuki, Ayumu Sugiyama, Eri Ishikawa, Takeshi Yoshikawa, Ken Sakata, and Ryo Takeuchi, J. Org. Chem., 2023, 88, 1545-1559. [LINK]
24.
Synthesis of azafluoranthenes by iridium-catalyzed [2 + 2 + 2] cycloaddition and evaluation of their fluorescence properties
Takahiro Sawano, Kaho Takamura, Tomoka Yoshikawa, Kayo Murata, Marina Koga, Risa Yamada, Takahide Saito, Kazumasa Tabata, Yugo Ishii, Wataru Kashihara, Tatsuya Nishihara, Kazuhito Tanabe, Tadashi Suzuki and Ryo Takeuchi, Org. Biomol. Chem., 2023, 21, 323-331. [LINK]
23.
Recent advances in iridium-catalyzed enantioselective allylic substitution using phosphoramidite-alkene ligands
Takahiro Sawano, Ryo Takeuchi, Catal. Sci. Tec., 2022, 12, 4100-4112. [LINK]
22.
Iridium-catalyzed C3-selective asymmetric allylation of 7-azaindoles with secondary allylic alcohols
Takahiro Sawano, Takeshi Matsui, Marina Koga, Eri Ishikawa, Ryo Takeuchi, Chem. Commun., 2021, 57, 9684-9687. [LINK]
2016-2020
21.
Iridium-Catalyzed Hydroalkylation of Aliphatic Alkenes with β-Ketoesters: Formal Hydroalkylation with Methyl Ketones
Takahiro Sawano, Kei Ogihara, Jun Sagawa, Masaki Ono, and Ryo Takeuchi Org. Lett. 2020, 22, 6187−6191. [LINK]
20.
Regio- and Enantioselective Substrate-Directed Epoxidation
Takahiro Sawano and Hisashi Yamamoto Eur. J. Org. Chem. 2020, 2369–2378. [LINK]
19.
Synthesis of Anthraquinones by Iridium-Catalyzed [2 + 2 + 2] Cycloaddition of a 1,2-Bis(propiolyl)benzene Derivative with Alkynes
Takahiro Sawano, Yuko Toyoshima, Ryo Takeuchi, Inorganics, 2019, 7, 138. [LINK]
18.
Enantioselective Epoxidation of beta,gamma-Unsaturated Carboxylic Acids by a Cooperative Binuclear Titanium Complex
Takahiro Sawano and Hisashi Yamamoto ACS Catal. 2019, 9, 3384–3388 [LINK]
17.
Substrate-Directed Catalytic Selective Chemical Reactions
Takahiro Sawano and Hisashi Yamamoto J. Org. Chem. 2018, 83, 9, 4889–4904. [LINK]
16.
Metal-organic layers stabilize earth-abundant metal-terpyridine diradical complexes for catalytic C-H activation
Zekai Lin,‡Nathan C. Thacker,‡ Takahiro Sawano,‡ Tasha Drake, Pengfei Ji, Guangxu Lan, Lingyun Cao, Shubin Liu, Cheng Wang and Wenbin Lin <‡ Co-First Author> Chem. Sci., 2018, 9, 143–151. [LINK]
15.
Cerium-Hydride Secondary Building Units in a Porous Metal-Organic Framework for Catalytic Hydroboration and Hydrophosphination
Pengfei Ji,† Takahiro Sawano,† Zekai Lin, Ania Urban, Dean Boures, and Wenbin Lin <† Co-First Author> J. Am. Chem. Soc. 2016, 138, 14860−14863. [LINK]
14.
Metal-Organic Frameworks Stabilize Mono(phosphine)-Metal Complexes for Broad-Scope Catalytic Reactions
Takahiro Sawano, Zekai Lin, Dean Boures, Bing An, Cheng Wang, and Wenbin Lin, J. Am. Chem. Soc. 2016, 138, 9783−9786. [LINK]
2008-2015
13
Robust, Chiral, and Porous BINAP-Based Metal-Organic Frameworks for Highly Enantioselective Cyclization Reactions
Takahiro Sawano, Nathan C. Thacker, Zekai Lin, Alexandra R. McIsaac, and Wenbin Lin J. Am. Chem. Soc. 2015, 137, 12241−12248. [LINK]
12.
Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes
Takahiro Sawano, Minoru Hashizume, Shouta Nishimoto, Keiyu Ou, and Takahiro Nishimura* Org. Lett. 2015, 17, 2630−2633. [LINK]
11.
The first chiral diene-based metal-organic frameworks for highly enantioselective carbon-carbon bond formation reactions
Takahiro Sawano, Pengfei Ji, Alexandra R. McIsaac, Zekai Lin, Carter W. Abney and Wenbin Lin* Chem. Sci., 2015, 6, 7163. [LINK]
10.
Privileged Phosphine-Based Metal−Organic Frameworks for Broad Scope Asymmetric Catalysis
Joseph M. Falkowski,† Takahiro Sawano,† Teng Zhang, Galen Tsun, Yuan Chen, Jenny V. Lockard, and Wenbin Lin*, J. Am. Chem. Soc. 2014, 136, 5213−5216. [LINK]
9.
Cobalt-Catalyzed Asymmetric Addition of Silylacetylenes to 1,1-Disubstituted Allenes
Takahiro Sawano, Keiyu Ou, Takahiro Nishimura,*, and Tamio Hayashi J. Org. Chem. 2013, 78, 8986−8993. [LINK]
8.
Cobalt-Catalyzed Asymmetric 1,6-Addition of (Triisopropylsilyl)-acetylene to α,β,γ,δ-Unsaturated Carbonyl Compounds
Takahiro Sawano, Akram Ashouri, Takahiro Nishimura and Tamio Hayash J. Am. Chem. Soc. 2012, 134, 18936−18939. [LINK]
7.
Cobalt-catalyzed asymmetric addition of silylacetylenes to oxa- and azabenzonorbornadienes
Takahiro Sawano, Keiyu Ou, Takahiro Nishimura* and Tamio Hayashi* Chem. Commun., 2012, 48, 6106–6108. [LINK]
6.
Cobalt-catalyzed conjugate addition of silylacetylenes to a,b-unsaturated ketones
Takahiro Nishimura,* Takahiro Sawano, Keiyu Ou and Tamio Hayashi Chem. Commun., 2011, 47, 10142–10144. [LINK]
5.
Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes
Xun-Xiang Guo, Takahiro Sawano, Takahiro Nishimura, Tamio Hayashi Tetrahedron Asymmetry 2010, 21, 1730-1736. [LINK]
4.
Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to r,,γ,δ-Unsaturated Carbonyl Compounds
Takahiro Nishimura,* Yuichi Yasuhara, Takahiro Sawano, and Tamio Hayashi* J. Am. Chem. Soc. 2010, 132, 7872–7873. [LINK]
3.
Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes
Takahiro Nishimura,* Takahiro Sawano, Sumito Tokuji and Tamio Hayashi* Chem. Commun., 2010, 46, 6837–6839. [LINK]
2.
Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones with Alkynylsilanols
Takahiro Nishimura,* Sumito Tokuji, Takahiro Sawano, and Tamio Hayashi Org. Lett. 2009, 11, 3222-3225. [LINK]
1.
Asymmetric Synthesis ofb-Alkynyl Aldehydes by Rhodium-CatalyzedConjugate Alkynylation
Takahiro Nishimura,* Takahiro Sawano, and Tamio Hayashi Angew. Chem. Int. Ed. 2009, 48, 8057 –8059. [LINK]